Types of nanocomposites

Tough Nanocomposites: The Role of Carbon Nanotube Type

Abstract ImageDepartment of Materials and Interfaces, Weizmann Institute of Science, Rehovot, Israel 76100

Nano Lett., 2009, 9 (4), pp 1423–1426

DOI: 10.1021/nl803241y

Section:

Abstract

Unusually large deformation is observed in poly(methyl metacrylate) (PMMA) electrospun fibers under tension when multiwall or single-wall carbon nanotubes (MWCNTs and SWCNTs) are included as a second phase in the fibers. These distortions are virtually absent in pure PMMA fibers and stem from markedly different energy dissipation mechanisms and necking modes arising from the dissimilar nanotube morphologies. Thus, both nanotubes types are effective tougheners of PMMA fibers, with an advantage for MWCNTs over SWCNTs.

Citing Articles

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Cover ImageThis article has been cited by 3 ACS Journal articles (3 most recent appear below).

  • Junchun Yu, Bounphanh Tonpheng, Gerhard Gröbner, and Ove Andersson

    Macromolecules2012 45 (6), 2841-2849

  • A MWCNT/Polyisoprene Composite Reinforced by an Effective Load Transfer Reflected in the Extent of Polymer Coating

    Junchun Yu, Bounphanh Tonpheng, Gerhard Gröbner, and Ove Andersson

    Tensile and microstructural properties of multiwall carbon nanotube (MWCNT)/polyisoprene (PI) composites have been investigated after cross-linking achieved purely by simultaneous high-pressure high-temperature treatment. The method enables gradual ...

  • Karen Young, Fiona M. Blighe, Juan J. Vilatela, Alan H. Windle, Ian A. Kinloch, Libo Deng, Robert J. Young, and Jonathan N. Coleman

    ACS Nano2010 4 (11), 6989-6997

      Strong Dependence of Mechanical Properties on Fiber Diameter for Polymer−Nanotube Composite Fibers: Differentiating Defect from Orientation Effects

      Cover ImageKaren Young, Fiona M. Blighe, Juan J. Vilatela, Alan H. Windle, Ian A. Kinloch, Libo Deng, Robert J. Young, and Jonathan N. Coleman

      We have prepared polyvinylalcohol−SWNT fibers with diameters from 1 to 15 μm by coagulation spinning. When normalized to nanotube volume fraction, Vf, both fiber modulus, Y, and strength, σB, scale strongly with fiber diameter, D: Y/Vf D−1.55 and σB/Vf ...

  • Chih-Wei Lin and Arnold C.-M. Yang

    Macromolecules2010 43 (16), 6811-6817

      Nanoplastic Interactions of Surface-Grafted Single-Walled Carbon Nanotubes with Glassy Polymer Chains in Nanocomposites

      Chih-Wei Lin and Arnold C.-M. Yang

      The nanoscopic interactions between glassy macromolecules and the dispersed single-walled carbon nanotubes (SWCNTs) in a nanocomposite during very large local elongations were revealed. The results also unveiled a unique mode of molecular motions followed ...

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    Nanjundan Ashok Kumar, Sung Hun Kim, Jong Tae Kim, Kwon Taek Lim, Yeon Tae Jeong (2008) Study on cluster formation of poly 2- hydroxyethyl methacrylate functionalized single-walled carbon nanotubes Surface Review and letters 15: 5. 1-9 October
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    Nanjundan Ashok Kumar, Hullathy Subban Ganapathy, Jong Su Kim, Yong Seok Jeong, Yeon Tae Jeong (2008) Preparation of poly 2-hydroxyethyl methacrylate functionalized carbon nanotubes as novel biomaterial nanocomposites European Polymer Journal 44: 3. 579-586 March
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